Ethanol-Processable, Highly Crystalline Conjugated Polymers for Eco-Friendly Fabrication of Organic Transistors and Solar Cells
2017
We report eco- and human-friendly fabrication of organic field-effect transistors (OFETs) and polymer solar cells (PSCs) using only ethanol as a processing solvent at ambient condition, in stark contrast to that involving the use of halogenated and/or aromatic solvents. New ethanol-processable electroactive materials, p-type polymer (PPDT2FBT-A) and n-type bis-adduct fullerene acceptor (Bis-C60-A) are designed rationally by incorporation of oligoethylene glycol (OEG) side-chains. By ethanol processing, PPDT2FBT-A shows a broad light absorption in the range of 300–700 nm and highly crystalline interchain ordering with out-of-plane interlamellar scattering up to (400) with strong π–π stacking. As a result, the ethanol-processed PPDT2FBT-A OFETs yield high charge-carrier mobilities up to 1.0 × 10–2 cm2 V–1 s–1, which is the highest value reported to date from alcohol-processed devices. Importantly, the ethanol-processed PPDT2FBT-A OFET outperformed that processed using typical processing solvent, chlorobenze...
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