2,5-Di-(tert-butyl)phospholyl sandwich complexes containing group 14 elements (Ge, Sn, Pb). Synthesis, molecular structure, and ring transfer chemistry of [M(PC4H2But2)2] (M= Sn, Pb)

Kareen Forissier,Louis Ricard,Duncan Carmichael,François Mathey

2,5-Di-(tert-butyl)phospholyl sandwich complexes containing group 14 elements (Ge, Sn, Pb). Synthesis, molecular structure, and ring transfer chemistry of [M(PC4H2But2)2] (M= Sn, Pb)

1999

Kareen Forissier
Louis Ricard
Duncan Carmichael
François Mathey

Structurally characterised tin and lead sandwich compounds are shown to contain aromatic phospholyl ligands which can be transferred to rhodium and iridium centres under mild conditions.

Keywords:

Rhodium
Molecule
Iridium
Carbon group
Organic chemistry
Inorganic chemistry
Tin
Chemistry
Ligand
tert butyl

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