Synthesis and Revision of the Relative Configuration of Glabramycin B.
2016
Abstract The stereostructure of glabramycin B, which is an antibacterial 10-membered lactone fused with 4-oxygenated cyclohexanone, was presumed on comparison with related compounds, and concise synthesis of our proposed structure of glabramycin B was achieved via dianion alkylation, Shiina’s lactonization, and Stille cross coupling. We succeeded in the reassignment of its relative configuration.
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