Formative and Controlled Mechanisms of Nano-sized γ′ Precipitates with Local Phase-transition within Dislocation Networks of Nickel-based Single Crystal Superalloys
2021
Abstract The chemical and structural evolution within dislocation networks are investigated in a nickel-based single crystal superalloy crept under 1373K and 137MPa. The local region within dislocation networks can be divided to two separated parts: gridlines which compose the arrangements of dislocation networks and mesh regions as intervals between gridlines. With evolution of dislocation networks, precipitation of nano-sized γ′ phase (γ′n) are observed in mesh region, while gridlines always display the FCC feature of γ phase. The formative mechanism of γ′n is revealed as increased segregations of Cr, Co and Re along gridlines which enhance the contents of γ′-rich elements such as Al in mesh region to promote the local phase transition from FCC to highly ordered L12. However, growth of γ′n requires massive diffusion of γ′-rich elements that is confined by the chemical barrier along gridlines with strong segregations of Cr, Co and Re. The mesh region of γ′n and gridlines of γ reinforce each other forming potential γ/γ′ substructures to stabilize the dislocation networks during creep. Denser dislocation networks formed in dendrite core under larger local lattice misfit are accompanied with facilitated formation of γ/γ′ substructures which derive higher creep resistance than interdendritic region.
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