Magnetic–Nonmagnetic Phase Transition with Interlayer Charge Disproportionation of Nb3 Trimers in the Cluster Compound Nb3Cl8
2017
We grew large single crystals of the cluster magnet Nb3Cl8 with a magnetic triangular lattice and investigated its magnetic properties and crystal structure. In Nb3Cl8, the [Nb3]8+ cluster has a single unpaired spin, making it an S = 1/2 triangular lattice anti-ferromagnet. At low temperatures, Nb3Cl8 exhibits a magnetic–nonmagnetic phase transition driven by a charge disproportionation, in which the paramagnetic [Nb3]8+ clusters transform into alternating layers of nonmagnetic [Nb3]7+ and [Nb3]9+ clusters. The observed exotic phenomenon with the strong correlation between the magnetism and structure are based on the nature of the cluster magnetism.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
34
References
20
Citations
NaN
KQI