Synthesis of 6-Adamantyl-2-pyridone and Reversible Hydrogen Activation by the Corresponding Bis(perfluorophenyl)borane Complex
2020
We herein describe the two-step synthesis of 6-adamantyl-2-pyridone from 1-acetyladamantane. The borane complex derived from 6-adamantyl-2-pyridone and the Piers borane liberates dihydrogen at 60 °C. The reverse reaction, hydrogen activation by the formed pyridonate borane is accomplished under mild conditions. The mechanism of the hydrogen activation is studied by DFT computations.
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
10
References
0
Citations
NaN
KQI