A method of producing estolideshaving high structure stability

In one embodiment of the invention, a) preparing a fatty acid mixture derived from the maintenance of biomass; b) separating the fatty acid mixture to C16 fatty acids and C18 fatty acids; c) the step of converting the fatty acid C18 to C18 linear internal olefins or C17; Discloses a method for manufacturing a high structural stability S. Toll fluoride containing; and d) the C18 or C17 linear internal olefin and the step of the C16 fatty acid to the reaction producing the S-S toll fluoride toll fluoride.