Synthesis and light-emitting properties of carbazole-based copolymers bearing cyano-substituted arylenevinylene chromophore Part A Polymer chemistry
2010
Two arylenevinylene compounds bearing the cyano group at α-position (6) and β-position (9) from the dialkoxylphenylene unit were synthesized, in which the molecular termini were functionalized with 3-bromocarbazole. The Suzuki coupling copolymerization of these compounds with 1,4-bis[(3'-bromocarbazole-9'-yl)methylene]-2,5-didecyloxybenzene and 9,9-dihexylfluorene-2,7-bis(boronic acid) was carried out to obtain copolymers (cp67 and cp97) containing the cyano-substituted arylenevinylene fluorophore of 7 mol %. Model compounds (6' and 9') corresponding to the arylenevinylene fluorophore were also prepared. The UV spectra of copolymers resembled that of homopolymer hp with no arylenevinylene segment in both CHCl₃ solution and thin film. The emission maxima of copolymers in CHCl₃ (394 nm) agreed with that of homopolymer indicating that the emission bands originated from the carbazole-fluorene-carbazole segment. The emission maximum wavelength of copolymer cp67 in thin film (477 nm) indicated fluorescence from the cyano-substituted arylenevinylene fluorophore because of the occurrence of fluorescence resonance electron transfer. In contrast, copolymer cp97 showed fluorescence at 528 nm to suggest the formation of a new emissive species such as a charge-transfer complex (exciplex).
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
0
References
0
Citations
NaN
KQI