Process for the preparation of 3 (4), 7 (8) -dihydroxymethyl-bicyclo (4.3.0) nonane
2006
method
for the preparation of 3 (4), 7 (8) -dihydroxymethyl-bicyclo [4.3.0] nonane by hydroformylation
of bicyclo [4.3.0] nona-3,7-diene
with subsequent hydrogenation, characterized in that bicyclo [4.3.0] nona-3,7-diene
in homogeneous organic phase in the presence of triarylphosphines
complexed rhodium compounds and excess triarylphosphine
at temperatures of 70 to 160 ° C
and pressing
from 10 to 30 MPa with synthesis gas, where rhodium in
a concentration of 10 to 500 ppm by weight, based on the homogeneous
Reaction mixture is used and wherein the molar ratio of rhodium
to phosphorus is 1:10 to 1: 200,
and the thus obtained 3 (4), 7 (8) -bisformyl-bicyclo [4.3.0] nonane subsequently to
Hydrogenated 3 (4), 7 (8) -dihydroxymethyl-bicyclo [4.3.0] nonane.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
0
References
0
Citations
NaN
KQI