Cloud point extraction for determination of cadmium in soft drinks by thermospray flame furnace atomic absorption spectrometry

Abstract Cloud point extraction (CPE) is proposed as a preconcentration procedure for the determination of Cd in soft drinks by thermospray flame furnace atomic absorption spectrometry (TS-FF-AAS). The cadmium reacted with pyridyl-azo-naphthol (PAN) to form hydrophobic chelates, which were extracted into the micelles of Triton X-114 in a solution buffered at pH 9. NaCl was used for the phase separation. The variables which affect the preconcentration were optimized using a 2 3 factorial design and central composite design (CCD). A response surface maximum point was obtained, and the critical values were a concentration of 0.13 mmol L − 1 PAN, 0.03% m/v Triton X-114 and 2.3% m/v NaCl. Under the optimized conditions, after the extraction and preconcentration steps, a sample volume of 100 μL was introduced into the hot Ni tube using water as the carrier at a flow rate of 0.4 mL min − 1 . The values obtained for the detection limit, relative standard deviation and preconcentration factor were 0.0178 μg L − 1 , 4.1% (n = 8) and 55.5, respectively. The accuracy of the proposed method was demonstrated by performing addition-recovery experiments. Recoveries varied from 88 to 104%.