SYNTHESIS OF PENTADIENYLIUM IONS WITH N-SILYLATED PHOSPHAIMINES, CHARACTERIZATION AND REACTIVITY

M. P. Fialon,Marie Rose Mazières,Yves Madaule,Corinne Payrastre,Michel Sanchez,J. G. Wolf,A. O. Gudima,V. D. Romanenko

SYNTHESIS OF PENTADIENYLIUM IONS WITH N-SILYLATED PHOSPHAIMINES, CHARACTERIZATION AND REACTIVITY

1995

M. P. Fialon
Marie Rose Mazières
Yves Madaule
Corinne Payrastre
Michel Sanchez
J. G. Wolf
A. O. Gudima
V. D. Romanenko

Abstract By condensation of a carboxonium salt with N-silylated phosphaimines new types of pentadienylium salts are obtained. These new compounds are characterized by NMR spectroscopy, UV and mass spectra. Their aza-Wittig reactivity towards isocyanides is described.

Keywords:

Inorganic chemistry
Mass spectrum
Nuclear magnetic resonance spectroscopy
Organic chemistry
Ion
Chemistry
Photochemistry
Condensation

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