On the chemistry of flavin-dependent oxygen activation III. synthesis of 1.10a-dihydroflavin and its 10.10-aring opened derivative as model chromophores for enzyme-bound intermediates
1980
Abstract Model chromophores of 1.10-dihydroflavin and its 10.10a-ring opened derivative have been isolated. By comparison with enzymatic intermediates, reaction mechanisms of flavin-dependent oxygenase and luciferase are discussed in terms of chemical structure.
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