Probing the solvent-induced tautomerism of a redox-active ureidopyrimidinone.

Anne-Marie Alexander,Marc Bria,Gunther Brunklaus,Stuart T. Caldwell,Graeme Cooke,James F. Garety,Shanika G. Hewage,Yann Hocquel,Niall McDonald,Gouher Rabani,Georgina M. Rosair,Brian O. Smith,Hans Wolfgang Spiess,Vincent M. Rotello,Patrice Woisel

Probing the solvent-induced tautomerism of a redox-active ureidopyrimidinone.

2007

Anne-Marie Alexander
Marc Bria
Gunther Brunklaus
Stuart T. Caldwell
Graeme Cooke
James F. Garety
Shanika G. Hewage
Yann Hocquel
Niall McDonald
Gouher Rabani
Georgina M. Rosair
Brian O. Smith
Hans Wolfgang Spiess
Vincent M. Rotello
Patrice Woisel

A ferrocene-functionalised ureidopyrimidinone has been synthesised that can signal the solvent-induced tautomerism of the dimeric 4[1H]-pyrimidinone form to the monomeric 6[1H]-pyrimidinone form.

Keywords:

Redox
Tautomer
Solvent
Organic chemistry
Chemistry
Monomer
Inorganic chemistry
Polymer chemistry
redox active

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