Single-phased white-light emitting CaAl2Si2O8: Eu2+, Mn2+ phosphors prepared by a sol―gel method

2009 
CaAl2Si2O8: Eu2+, Mn2+ phosphors have been prepared by a sol–gel method. X-ray diffractometer, spectrofluorometer and UV–Vis spectrometer were used to characterize structural and optical properties of the samples. The results indicate that anorthite (CaAl2Si2O8) directly crystallizes at 1000 °C in the sol–gel process. CaAl2Si2O8: Eu2+, Mn2+ phosphors show two emission bands excited by ultraviolet light. Blue (around 415 nm) and yellow (around 575 nm) emissions originate from Eu2+ and Mn2+, respectively. With appropriate tuning of Mn2+ content, CaAl2Si2O8: Eu2+, Mn2+ phosphors exhibit different hues and relative color temperatures.
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