Mn3+-Mediated Coupling-Cyclization of 5-Arylpent-1-enes with Active Methylene Compounds by Electrooxidation.

R. Shundo,Ikuzo Nishiguchi,Yoshiharu Matsubara,Tsuneaki Hirashima

Mn3+-Mediated Coupling-Cyclization of 5-Arylpent-1-enes with Active Methylene Compounds by Electrooxidation.

1992

R. Shundo
Ikuzo Nishiguchi
Yoshiharu Matsubara
Tsuneaki Hirashima

Selective coupling-cyclization of 5-arylpent-1-enes with active methylene compounds was developed by indirect electrooxidation using a small amount of Mn(OAc)2·4H2O to give 1-[2,2-(disubstituted)ethyl]tetralines in good yields.

Keywords:

Methylene
Organic chemistry
Chemistry

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