Approaches Towards Enkephalin Analogs Exhibiting Two Catechol Units
2005
Peptide-bridged dicatechols were prepared by a combination of solid- and solution-phase synthesis. The target compounds are potential precursors for constrained metal containing enkephalin analogs. While a simple model compound selectively forms a metallamacrocycle with the cis-molybdenum(VI)dioxo unit, this goal could not be achieved with the corresponding peptide bridged derivatives.
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