Regioselective synthesis of 6-aryl-5-(chloroethyl)salicylates by domino ‘[3+3] cyclization/homo-Michael’ reactions of 1,3-bis(silyloxy)-1,3-butadienes with 1-formyl- and 1-acetyl-1-aroyl-cyclopropanes

Abdolmajid Riahi,Matthias Lau,Helmut Reinke,Christine Fischer,Peter Langer

Regioselective synthesis of 6-aryl-5-(chloroethyl)salicylates by domino ‘[3+3] cyclization/homo-Michael’ reactions of 1,3-bis(silyloxy)-1,3-butadienes with 1-formyl- and 1-acetyl-1-aroyl-cyclopropanes

2009

Abdolmajid Riahi
Matthias Lau
Helmut Reinke
Christine Fischer
Peter Langer

Abstract Functionalized 3-aryl-4-(chloroethyl)phenols are regioselectively prepared by domino ‘[3+3] cyclization/homo-Michael’ reactions of 1,3-bis(silyloxy)-1,3-butadienes with 1-formyl- and 1-acetyl-1-aroyl-cyclopropanes.

Keywords:

Aldehyde
Chemical synthesis
Domino
Aryl
Chemistry
Regioselectivity
Biphenyl
Organic chemistry
Michael reaction
Phenols

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