Reactions of boron trifluoride with allylic boranes and 1-boraadamantane
2007
The reactions of boron trifluoride with triallyl- and allyldialkylboranes represent a convenient non-catalytic approach to allyl(difluoro)boranes. The rupture of 1-boraadamantane core with BF 3 leads to 3-fluoro-7-difluoroborylmethyl-3-borabicyclo-[3.3.1]nonane derivatives.
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