Synthesis and Diels?Alder Reactivity of ortho-Carbazolequinones.
2005
Oxidation of 2- and 3-hydroxycarbazoles with Fremy's salt gave the corresponding ortho-carbazolequinones. These molecules react as carbodienophiles in Diels-Alder reaction with 1-acetoxy-1,3-butadiene and 1,3-cyclopentadiene to provide the novel benzocarbazolequinone structures 15, 16, 18 and 19.
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