Tip-Enhanced Raman Nanospectroscopy of Smooth Spherical Gold Nanoparticles
2020
We record nanoscale-resolved chemical images of thiobenzonitrile (TBN)-functionalized smooth gold nanospheres on silicon via tip-enhanced Raman (TER) nanospectroscopy. The recorded images trace the nascence of the familiar doughnut-shaped scattering profile of nanoparticles on silicon at its origin (the particle surface), which appears as a horseshoe-shaped scattering pattern under our experimental conditions. The local optical field maps are in agreement with their simulated finite-difference time-domain analogues. Analysis of the recorded spectra with the aid of ab-initio-molecular-dynamics-based Raman spectral simulations further suggests that optical rectification and molecular charging take place throughout the course of atomic-force-microscopy-based TER nanoscale chemical imaging.
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