A New Strategy for Fuel Desulfurization by Molecular Inclusion with Copper(II)-β-cyclodextrin@SiO2@Fe3O4 for Removing Thiophenic Sulfides

Developing a new and environment-friendly desulfurization strategy for removing thiophenic sulfides from fuel is currently necessary. Fuel desulfurization by molecular inclusion with a novel cyclodextrin-based magnetic nanomaterial copper(II)-β-cyclodextrin@silica@ferroferric oxide (Cu(II)-β-CD@SiO2@Fe3O4) was proposed for the efficient removal of thiophene (T), benzothiophene (BT), and dibenzothiophene (DBT) in fuel. Cu(II)-β-CD@SiO2@Fe3O4 was successfully prepared by the reaction between mono-6-O-toluenesulfonyl-Cu(II)-β-CD and 3-aminopropyltrimethoxysilane functionalized SiO2@Fe3O4, and the structural characterization illustrated that the active desulfurization component Cu(II)-β-CD was evenly immobilized on the surface of SiO2@Fe3O4. Furthermore, Cu(II)-β-CD@SiO2@Fe3O4 showed outstanding desulfurization performance for thiophenic sulfides in the order BT > DBT > T on account of the varying molecular inclusion ability of Cu(II)-β-CD for the three types of thiophenic sulfides. The optimum immobilized lo...