Enantioselective synthesis induced by tetrathia-[7]-helicenes in conjunction with asymmetric autocatalysis
2006
Highly enantioenriched 5-pyrimidyl alkanol was formed using tetrathia-[7]-helicenes as a chiral initiator in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, in conjunction with asymmetric autocatalysis.
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