Critical addition of Ti to maintain the Tc of (Bi1-zTiz)1.6Pb0.4Sr2Ca2Cu3Ox above 100 K

1993 
Influence of Ti addition (substitution for Bi) on Tc is studied for high Tc (Bi1-zTiz)1.6Pb0.4Sr2Ca2Cu3Ox. We found a critical Ti addition to keep high Tc (above 100 K) of the (Bi1-zTiz)1.6Pb0.4Sr2Ca2Cu3Ox. The high-Tc phase can be found up to 0.5 of z. It is explained by an abnormal Tc change which is found from 0.3 to 0.5 of z. Based on results of the electrical resistivity and x-ray diffraction, an abnormal Tc change is discussed.
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