Quantum tunnelling of the magnetization in a monolayer of oriented single-molecule magnets

Single-molecule magnets are molecular complexes with magnetic bistability, and recently it was shown that such a magnetic memory effect is retained for Fe4 clusters when they are wired to a gold surface. These authors have tailored the clusters to have a preferential orientation and form a self-assembled monolayer on the surface. It then becomes possible to observe quantum tunnelling of the magnetization, which shows up as steps in the magnetic hysteresis loop.