Snap frozen! Capturing two metastable polymorphs in a tetramorphic one-dimensional coordination polymer constructed from cadmium, dithiophosphate, and 4-pyridinealdazine

Four polymorphs are described for the one-dimensional coordination polymer {Cd[S2P(OMe)2]2(4-pyridine-aldazine)}n (1) which features a trans-N2S4 distorted octahedral coordination geometries. Latti...