Asymmetric synthesis. 21. The first enantioselective synthesis of natural (+)-tetraponerine-8: a new extension of the CN(R,S) method to an uncommon skeleton.
1990
The first synthesis of natural (+)-tetraponerine-8 (1) has been accomplished in six steps from 2-cyano-6-oxazolopiperidine synthon and has allowed assignment of the absolute configuration
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