Electronic spectra of cationic PAH and PAH clusters

An experiment designed for measuring the electronic spectra of PAH cations and PAH cluster cations has been set up, which is briefly described. The photodissociation spectra, reflecting the absorption spectra, of 2-methyl-naphthalene dimer cation have been recorded in the spectral ranges corresponding to the transitions from the ground state to both the excited charge resonance state and the first allowed local electronic excitation state.