Photochemistry of Silylimines: Diels-Alder Trapping of a Photochemically Generated o-Quinodimethane Intermediate from o-(N-Trimethylsilyliminomethyl)toluene.
1990
o-(N-Trimethylsilyliminomethyl)toluene on irradiation underwent γ-hydrogen transfer to give an o-quinodimethyane intermediate which could be trapped with dimethyl fumarate, dimethyl maleate, trans-methyl cinnamate, methyl acrylate, acrylonitrile and the imine itself; under identical conditions o-(N-t-butyliminomethyl)toluene was inert.
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