Unusual platinum complexes in the gas phase
2016
Previously unknown cationic platinum complexes Pt(C5H4N)(C5H5N)+ and Pt(C5H4N)+, where platinum atom forms an unusual three-membered metallacycle with a deprotonated pyridine molecule, were detected in the gas phase by mass spectrometry and structurally characterized by DFT quantum-chemical calculations.
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