Organometallic products from the reaction of the isoelectronic Mn(CO)5- and Cr(CO)4NO- metallate anions with bis-α-bromocyclopropyl ketone

Mn(CO)5− and Cr(CO)4NO− react with the title ketone to give organometallic products. In the chromium case, a single metallofuran product is produced. In the manganese reaction, one can isolate a series of four complexes, two of which have a structure closely related to the chromium complex. The other two complexes are assigned an acyl manganese structure. The structures of the chromium complex and one of the acyl manganese complexes have been determined by X-ray methods. One finds a distorted octahedral bonding about the metal atom in each case. The chromium complex has bond lengths very similar to those reported for a closely related manganese structure, implying a delocalization of electrons within a metallofuran ring. As expected for this mixed carbonyl nitrosyl complex, the nitrosyl group is positioned trans to the oxide bond, representing the weakest and strongest "trans-effect" substituents. The acyl manganese structures contain an Mn(CO)4 unit in contrast to the usual Mn(CO)5 acyl complexes, with t...