One pot synthesis of substituted dihydroindeno[1,2-b]indoles and dihydrobenzo[a]carbazoles by photostimulated reactions of o-iodoaniline with carbanions by the SRN1 mechanism
2006
The photostimulated reaction of enolate anions of cyclic aromatic ketones such as substituted indan-1-ones and 3,4-dihydro-2H-naphthalen-1-one with o-iodoaniline in DMSO affords 1-, 2-, 3-, and 4-methoxy-5,10-dihydroindeno[1,2-b]indoles (34-40%), 1,2-, 1,4-, and 2,3-dimethoxy-5,10-dihydroindeno[1,2-b]-indoles (31-43%), and 1-, 2-, and 3-methoxy-5,11-dihydro-6H-benzo[a]carbazoles (42-61%) by the SRN1 mechanism in one pot reactions.
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