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Stereoselective SE2′ Additions of Enantioenriched Allylic Tin and Indium Reagents to Protected Threose and Erythrose Aldehydes: A General Strategy for the Stereocontrolled Synthesis of Precursors to the Eight Diastereomeric Hexoses an
2010
The enantioenriched (∼90−95% ee) α-alkoxy allylic stannanes (S)- and (R)-2.1 undergo in situ transmetallation with InCl3 in EtOAc and subsequent SE2‘ addition to aldehydes to afford anti adducts 3....
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