Determination of the rate of a fast exchanging coordinated molecule in a lanthanide(III) complex by proton NMR
2008
An elementary procedure is proposed and applied to study the exchange rate of a solvent or solute molecule bound to a complexed paramagnetic Ln(III) ion, other than Gd(III), from the measured longitudinal and transverse relaxation rates and paramagnetic resonance frequency shift at a given temperature.
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