A Diels—Alder Approach to the Enantioselective Construction of Fluoromethylated Stereogenic Carbon Centers.

Kazutaka Shibatomi,Fumito Kobayashi,Akira Narayama,Ikuhide Fujisawa,Seiji Iwasa

A Diels—Alder Approach to the Enantioselective Construction of Fluoromethylated Stereogenic Carbon Centers.

2012

Kazutaka Shibatomi
Fumito Kobayashi
Akira Narayama
Ikuhide Fujisawa
Seiji Iwasa

Diels—Alder reactions of β-fluoromethylacrylates in the presence of a Lewis acid activated chiral oxazaborolidine catalyst provide access to fluoromethylated cyclohexenes with very high enantioselectivity.

Keywords:

Bridged compounds
Stereocenter
Lewis acids and bases
Enantioselective synthesis
Carbon
Cyclohexenes
Catalysis
Organic chemistry
Chemistry
Chirality (chemistry)

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