Palladium‐Catalyzed Direct Benzylation of Polyfluoroarenes with Benzyl Carbonates through Selective C−H Functionalization
2016
A novel and efficient palladium-catalyzed cross-coupling benzylation reaction of pentafluorobenzene through selective C−H functionalization has been developed. A series of carbonates and polyfluorobenzenes have been examined and found to give moderate to good yields. This transformation provides a new straightforward approach for the synthesis of fluorinated diarylmethanes.
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