Compatibility effect of radiation‐grafting‐functionalized styrene–butadiene–styrene on polyamide 6/styrene–butadiene–styrene blends

Styrene-butadiene-styrene (SBS) was grafted with dibutyl maleate (DBM), methacrylic acid (MAA), or maleic anhydride (MAH) by Co-60 gamma-rays. The grafted SBS was blended with polyamide 6 (PA6). The compatibility of the PA6/SBS blends was studied with scanning electron microscopy and rheological measurements. The results showed significant improvement in the compatibility of PA6 blended with MAH- or MAA-grafted SBS, with the former being more effective, whereas grafting DBM was ineffective in this respect. Mechanisms of the compatibility enhancement and ineffectiveness are discussed. (c) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 108: 1029-1036,2008.