Crystallographic and magnetic properties of (Cu1−xVx)V2S4 (x≈0.3) single crystals with the layered defect NiAs structure synthesized under high pressure

2011 
We report on the reproducible growth of (Cu1−xVx)V2S4 single crystals of sizable dimensions (∼0.3 mm) and homogeneous composition (x≈0.3) by means of high-pressure synthesis. The refinement of single crystal X-ray diffraction data indicates that the crystal structure is of the monoclinic defect NiAs-type, which consists of a stacking of VS2 layers with CdI2-type structure and chains of edge-sharing (Cu1−xVx)S6 octahedra. Layers and chains form a network of face-sharing octahedra with no Cu–V intra-chain ordering. A combined X-ray photoelectron spectroscopy and bond valence sum analysis indicates that the valence of the V and Cu ions are 3+ and 1+, respectively. Magnetic susceptibility measurements unveil the coexistence of a large Pauli-like and of a small Curie-like paramagnetic contributions, with no evidence of any long range order down to 2 K. This result suggests a picture of predominantly itinerant 3d V electrons with significant electron–electron correlations.
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