Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers Through NHC—Cu-Catalyzed Allylic Substitution Reactions with (iBu)2(Alkynyl)aluminum Reagents.

2011 
The enantioselective synthesis of small organic molecules containing readily differentiable alkyne and alkene groups such as (III) is described.
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