Zur Kenntnis der Chemie der Metallcarbonyle und der Cyanokomplexe in flüssigem Ammoniak, XXVII. : Über die Reaktion von C3F7Fe(CO)3[P(C6H5)3]J und C3F7Fe(CO)4J mit flüssigem Ammoniak / About the Reaction of C3F7Fe(CO)3[P(C6H5)3] I and C3F7Fe(CO)4I with liquid Ammonia
2014
The reaction of C₃F₇Fe(CO)₃[P(C₆H₅)₃] I with liquid ammonia yields, dependend on the reaction-time C₃F₇Fe(CO)₂(NH₃)₂I and [C₃F₇Fe(CO)₂(NH₃)₃] I. In the contrary, C₃F₇Fe(CO)₄ I undergoes ammonolysis forming NH₄F, NH₄I, NH₄NCO and CO (NH₂)₂. No stable iron-complex could be obtained.
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