Sulfur-mesoporous carbon composites in conjunction with a novel ionic liquid electrolyte for lithium rechargeable batteries
2008
Abstract Sulfur coated mesoporous carbon (S–C) composites have been synthesized and physically characterized by scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and thermogravimetric analysis. Firstly, the electrochemical properties of the S–C composite cathode materials were tested in a conventional electrolyte consisting of 1 mol/L lithium bistrifluoromethanesulfonimidate in poly(ethylene glycol) dimethyl ether to compare them with pure sulfur electrode. The capacity and cyclic stability of the S–C composite were improved. Then the S–C composites were tested in a novel ionic liquid electrolyte consisting of 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide and lithium bistrifluoromethanesulfonimidate. The capacity and cyclic stability of the S–C composite using the ionic liquid electrolyte were much better than for the sample tested in a conventional organic solvent electrolyte.
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