Modulating the Magnetic Properties of Copper(II)/Nitroxyl Heterospin Complexes by Suppression of the Jahn-Teller Distortion.
2020
A series of six-coordinate
[Cu(L)L1][BF4]2 (L1 =
2,6-bis{1-oxyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-2-yl}pyridine) complexes are reported. Ferromagnetic
coupling between the Cu and L1 ligand spins is enhanced
by an L coligand with distal methyl substituents, which is attributed
to a sterically induced suppression of its Jahn–Teller distortion.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
70
References
2
Citations
NaN
KQI