Catalytic Asymmetric Aminolactonization of 1,2-Disubstituted Alkenoic Acid Esters: Efficient Construction of Aminolactones with an All-Carbon Quaternary Stereo-Center.

2014

The title reaction of alkenoic acid esters gives exclusively trans-γ and δ-lactones bearing the amino-functionality with high enantioselectivities.

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