Exhumation filling and paleo-pasteurization of the shallow petroleum system in the North Slope of the Biyang Sag, Nanxiang Basin, China

Abstract Deposits of biodegraded heavy oils are commonly encountered within the Eocene reservoir units in the North Slope of the Biyang Sag, Nanxiang Basin, eastern China. Oil physical property data and biomarkers show that these biodegraded oils occur only above burial depth equivalent to about 62 °C. This is much cooler than the cutoff temperature of biodegradation (about 80 °C), which has been interpreted within a complex petroleum evolution history that includes an early oil filling, significant uplift, a second phase of filling, and late-stage biodegradation. We use a new combination of fluid-inclusion analysis and calcite LA-ICP-MS U–Pb dating to obtain a temporal constraint on oil migration in the siliciclastic reservoirs. Two generations of oil inclusions, each showing a distinct fluorescence color (yellow and blue-green), were trapped before and after quartz cementation, respectively, which indicates multi-stage oil charge events. The early oil charge, marked by hydrostatic conditions and low-salinity pore waters, occurred during the late Eocene to early Oligocene burial period, corresponding to peak oil generation by basin modeling. The reservoirs were then refilled at a moderate-overpressure regime by higher maturity oils accompanied by high-salinity waters during the early Miocene exhumation. Reservoir sandstone-hosted, yellowish calcite veins, characteristic of 13C depletion and oil odor, contain primary blue-green fluorescent oil inclusions and bitumens, consistently pointing to precipitation from petroleum-derived fluids. LA-ICP-MS U–Pb dating of these vein calcites yields a U–Pb age of 19.6 ± 1.2 Ma, representing the latest timing of the second oil charge event in the North Slope. The isotope age of the fissure calcites near fault zones coincides well with the indirect age estimate based on fluid-inclusion homogenization temperature and the regional uplift stage. This scenario suggests that the Miocene tectonic compression not only triggered the recharge of oils but also facilitated the initiation or re-activation of faults that acted as conduits for oil migration. Reconstructed burial models show a continuous burial followed by significant uplift and erosion in this region. Since some reservoirs with maximum paleotemperature less than 80 °C were not sterilized during burial, the contained oils suffered from extensive biodegradation, presumably during the middle Miocene to present day. Thus, the shallower shutoff depth of biodegradation in this region was most likely ascribed to the paleo-pasteurization during burial, as opposed to later fresh oil replenishment or influx of shallow aquifers.