Specific capacitance of electrochemical capacitor using RuO2 loading arc-soot/activated carbon composite electrode

2009 
Abstract An AS-containing CNH and graphite ball was synthesized using a twin-torch-arc apparatus to make an electrode for an electrochemical capacitor with RuO 2 of metallic catalyst. The electrode was composed of activated material, graphite, and binder. RuO 2 -AS was prepared by oxidization of Ru-AS. The capacitance current of RuO 2 -AS electrode increases with an increase in the catalyst loading amount. RuO 2 -AS electrode in case of 4 wt.% RuO 2 has a capacitance current comparable to an AC electrode. The increase of specific capacitance for a composite electrode loading of 2 wt.% RuO 2 was 360% (16.6–60 F/g), while that for a loading of 4 wt.% was 640% (16.6–106 F/g). RuO 2 -AS electrodes have a smaller internal resistance than not only AC but also AS. Capacitance current of RuO 2 -AS/AC electrode is about twice that of AC electrode and RuO 2 -AS electrode. The RuO 2 -AS/AC electrode has a high specific capacitance and smaller internal resistance than AC electrode and RuO 2 -AS electrode.
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