Rotational Analyses of the Laser Induced Fluorescence Excitation Spectra of Jet-Cooled CF3O and CF3S

Abstract The high resolution, rotationally resolved laser induced fluorescence spectra for the A 2 A 1 ↔ X 2 E transitions of CF 3 O and CF 3 S were recorded. In addition to the origins, the symmetric vibrational band 3 0 1 and the nontotally symmetric bands 5 0 1 and 6 0 1 were analyzed for CF 3 O, while for CF 3 S the symmetric bands 1 0 1 , 2 0 1 , and 3 0 1 , as well as the nontotally symmetric bands 6 0 1 , 3 0 1 5 0 1 , and 3 0 1 6 0 1 , were analyzed.