Metal-Directed Formation of Three-Dimensional M3L2 Trigonal-Bipyramidal Cages
2001
The simple combination of two angular tritopic pyridine donor linkers (109° bond angle) with three ditopic platinum acceptors (90° bond angle) leads to essentially quantitative formation of self-assembled M3L2 trigonal-bipyramidal (TBP) supramolecular species.
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