Concentrating PGM from a PGM-Containing Ferroalloy by a Roast-Leach Process

A roasting-leaching process has been developed for concentrating platinum group metals (PGM) from a PGM-containing ferroalloy. The optimized roasting conditions used a NaOH-to-ferroalloy mass ratio of 1.2 at 600 °C for 2 h. The roasted product mainly comprised Na4SiO4, NaFeO2 and Fe2O3. The iron oxide and sodium silicate associated with the roasted product were leached in water and dilute sulfuric acid solution, while the PGM was concentrated in the acid-leached residue. A PGM concentration of 23.4% was obtained with assaying, and the concentration factor of PGM from the ferroalloy to PGM concentration was greater than 9.