The Metallic Nature of Two-Dimensional Transition-Metal Dichalcogenides and MXenes

ABSTRACT Metallic two-dimensional (2D) materials such as transition-metal dichalcogenides (TMDCs) and MXenes exhibit intriguing properties, including superconductivity, magnetism and electrocatalysis. Studies on the correlation between their nanoscale structures and properties can facilitate the development of photodetectors, supercapacitors, nanocatalysts, etc., but this topic has not been reviewed systematically. Here, we provide a comprehensive overview on the key factors that dictate the structures and properties of these 2D metals. We examine their phase transitions induced by structural or electronic modifications based on microscopic imaging, spectral characterization, and electrical measurements. From the perspective of surface and interface engineering, we elucidate the influences of lattice defects, dopants, and intercalated species between adjacent layers. Moreover, heterostructures involving highly conductive 2D component(s) are discussed, which may enable the observation of fascinating phenomena and/or synergistic effects due to the interlayer interactions. Finally, we provide insights into opportunities for new applications, e.g., radio-frequency antennas and electromagnetic interference shields. Feasible routes are also proposed to overcome the current challenges.