The Importance of Orbital Angular Momentum Contribution to Magnetic Moment: As an Important Example of Octahedral Macrocyclic Co(II) Complexes

Magnetic properties of Co+2 ion on new synthesized macrocyclic ligand was investigated with semi-theoretical approach. Calculations have shown that some parameters of magnetic Hamilton operator must take different values in order to obtain observed results. Calculations and experimental datas in the literature show that this structure has distorted octehedral geometry. However, calculations show that there is considerable amount of orbital contribution to magnetic moment.