Endohedrally Filled [Ni@Sn9]4‐and [Co@Sn9]5‐Clusters in the Neat Solids Na12Ni1‐xSn17 and K13‐xCo1‐xSn17: Crystal Structure and 119Sn Solid‐State NMR Spectroscopy.

Viktor Hlukhyy,Saskia Stegmaier,Leo van Wuellen,Thomas F. Faessler

Endohedrally Filled [Ni@Sn9]4‐and [Co@Sn9]5‐Clusters in the Neat Solids Na12Ni1‐xSn17 and K13‐xCo1‐xSn17: Crystal Structure and 119Sn Solid‐State NMR Spectroscopy.

2014

Viktor Hlukhyy
Saskia Stegmaier
Leo van Wuellen
Thomas F. Faessler

The title Zintl phases are prepared by reactions of the corresponding elemental alkali metals with pre-prepared M-Sn alloys (M: Ni, Co) at 550—880 °C for 48 h.

Keywords:

Solid-state nuclear magnetic resonance
Spectroscopy
Alkali metal
Crystal structure
Inorganic chemistry
Cluster (physics)
Chemistry

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